Product ID:N5219 RED A/D ENAMEL
MSDS Date:10/23/1997
FSC:8010
NIIN:00-527-3199
Status Code:A
MSDS Number: CKKTT

NILES CHEMICAL PAINT

907 CARROLL STREET
PERRY, GA 31069
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: TO226

NILES CHEMICAL PAINT

PERRY, GA 31069 US

Telephone: 616-683-3377

Cage: TO226

ALKYD RESIN SOLUTION

RTECS: AA1005880

Fraction By Weight: 52%

OSHA PEL 100

ACGIH TLV: 150

1-BUTYL ACETATE

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 29%

OSHA PEL 150

ACGIH TLV: 150

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE ( 22 MM @ 20 )

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 2%

OSHA PEL 100

ACGIH TLV: 100

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACRYLIC RESIN

RTECS: AA1004730

Fraction By Weight: 2%

ORGANOPHILIC CLAY

RTECS: OP1001769

Fraction By Weight: <1%

COBALT COMPOUNDS (AS CO)C.I. 77320

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1MG/M3

ACGIH TLV: 2MG/M3

BARIUM SULFATE

CAS: 7727-43-7

RTECS: CR0600000

RED PIGMENT

RTECS: RE1009220

Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION, LACRIMATION,
REDNESS, BLURRED VISION. SKIN: REDNESS AND IRRITATION, DEFATTING
OF THE SKIN LEADING TO DERMATITIS. BREATHING: NASAL AND
RESPIRATORY IRRITATION, CNS DEPRESSI ON ( DIZZINESS, DROWSINESS,
WEAKNESS, FATIGUE, CONFUSION ) NAUSEA, HEADACHE, VERTIGO, POSSIBLE
UNCONSCIOUSNESS, EVEN ASPHYXIATION. SWALLOWING: GASTROINTESTINAL
IRRITATION, ABDOMINAL PAIN, NAUSEA, VO MITING, DIARRHEA.
Effects of Overexposure:DERMATITIS, BLOOD, INCOHERENCE, CORNEAL
VACUOLIZATION, ANOREXIA, PROLONGED EXPOSURE TO SOLVENTS MAY CAUSE
CHRONIC HEALTH EFFECTS, EUPHORIA, NERVOUSNESS, INSOMNIA,
PARESTHESIA, PHOTOPHOBIA. TARGET ORG ANS: LIVER, KIDNEYS , EYES,
SKIN, RESPIRATORY SYSTEM, NUISANCE DUST, BLOOD, CNS, GI TRACT.

First Aid:INHALATION: MOVE VICTIM TO FRESH AIR AT ONCE. IF BREATHING
HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION
AS SOON AS POSSIBLE. SKIN CONTACT: WASH WITH SOAP AND WATER. EYE
CON TACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNT OF WATER FOR AT
LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER AND LOWER LIDS. GET
MEDICAL ATTENTION IMMEDIATELY. CONTACT LENSES SHOULD NOT BE WORN
WHEN WORKING WITH THIS MATERIAL. SWALLOWING: DRINK 1 OR 2 GLASES
OF WATER. DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point Method:TCC
Flash Point:=22.2C, 72.F
72F 22C TCC
Lower Limits:0.8
Upper Limits:7.1
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE AND FULL
PROTECTIVE CLOTHING. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESSURE BUILD UP AND POSSIBLE AUTO IGNITION OR
EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT , SPARKS , ELECTRICAL EQUIPMENT, AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION
TO HOT SURFACES REQUIRES S PECIAL PRECAUTIONS. DURING EMERGENCY
CONDITIONS, OVEREXPOSURE TO ***

Spill Release Procedures:ELIMAINATE ALL IGNITTION SOURCES. MINIMIZE
THE BREATHING OF VAPORS AND AVOID SKIN CONTACT. ABSORB WITH AN
INERT MATERIAL SUCH AS CLAY, SOIL, OR A COMMERCIALLY AVAILABLE
ABSORBENT. SHOVEL RECLAIMED LIQUID AND ABSORBENT INTO RECOVERY OR
SALVAGE DRUMS FOR DISPOSAL. *

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:* FOR LARGE SPILS: ELIMINATE ALL IGNITION SOURCES.
MINIMIZE THE BREATHING OF VAPORS AND AVOID SKIN CONTACT. DIKE TO
PREVENT FURTHER MOVEMENT AND RECLAIM INTO RECOVERY OR SALVAGE DRUMS
OR TANK TRUCK FOR DISPOSAL. OTHER PRECAUTIONS: CONTAINERS OF
THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY. **

Respiratory Protection:WEAR AN APPROPRIATE ( TYPE TC-23C-75 ) PROPERLY
FITTED HALF-MASK OF FULL FACEPIECE RESPIRATOR ( NIOGH/MSHA ) DURING
AND AFTER APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST
LEVELS ARE BELOW APPLICABLE LIMITS. FOLLOW RESPIRATOR
MANUFACTURER'S DIRECTIONS FOR USE.
Ventilation:SUFFICIENT VENTILATION IN VOLUME AND PATTERN SHOULD BE
PROVIDED
Protective Gloves:WEAR CHEMICAL RESISTANT ( NITRILE OR VITON ) GLOVES
AND CLOTHING
Eye Protection:FACE SHEILD OR GOGGLES
Other Protective Equipment:EMPLOYEES SHOULD WASH PROMPTLY WHEN SKIN
BECOMES CONTAMINATED. REMOVE ANY CLOTHING THAT BECOMES WET ( TO
AVOID FLAMMABILITY HAZARD ) AND WASH BEFORE REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
RESTROOM.
Supplemental Safety and Health
SUFFICIENT VENTILATION IN VOLUME AND PATTERN SHOULD BE PROVIDED TO KEEP
THE AIR CONCENTRATION BELOW CURRENT APPLICABLE OSHA OR ACGIH'S
LIMIT. REMOVE DECOMPOSITION PRODUCTS FORMED DURING WELDING OR FL
AME CUTTING OF SURFACES COATED WITH THIS PRODUCT. FOR BAKING
FINISHES--VENT VAPORS EMITTED ON HEATING.

Boiling Pt:>100.C, 212.F
B.P. Text:212-398 F ( 100-203 )
Spec Gravity:1.061
VOC Grams/Liter:2.99
Viscosity:70-75 KU
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:YES
Appearance and Odor:LIQUID, ODOR OF SOLVENTS
Percent Volatiles by Volume:40.81%
Corrosion Rate:MINIMAL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, NITRATES, ALKALIES, ACIDS, STRONG ACIDS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE, AND FEDERAL REGULATIONS.

Toxicological Information:DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.
SHOCK FROM DROPPING MAY SPLIT CONTAINER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:***DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD.
SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. GET MEDICAL ATTENTION.

Transport Information:DOT SHIPPING NAME (49CFR172.101-102) :
PAINT;3;UN1263;II DOT HAZARD CLAAIFICATION (49CFR172.101-102):
FLAMMABLE LIQUID DOT LABELS REQUIRED (49CFR172.101-102): FLAMMABLE
EPA HAZARDOUS WASTE CODE: D0 01 (IGNITABLE) U.S. POSTAL
REGULATIONS FORBID SENDING THIS PRODUCT THROUGH THE MAIL.

SARA Title III Information:OUR HAZARD EVALUATION HAS FOUND THIS PRODUCT
TO BE HAZARDOUS. THE PRODUCT SHOULD BE REPORTED UNDER THE
FOLLOWING EPA HAZARD CATEGORIES: IMMEDIATE ( ACUTE ) HEALTH
HAZARD, DELAYED ( CHRONIC ) H EALTH HAZARD, FIRE HAZARD.
FROM THE LIST OF TOXIC CHEMICALS, THIS PRODUCT CONTAINS: 1)
COBALT COMPOUNDS,
State Regulatory Information:OUR HAZARD EVALUATION HAS FOUND THIS
PRODUCT TO BE HAZARDOUS. THE PRODUCT SHOULD BE REPORTED UNDER THE
FOLLOWING EPA HAZARD CATEGORIES: IMMEDIATE ( ACUTE ) HEALTH
HAZARD, DELAYED ( CHRONIC ) HEALTH HAZARD, FIRE HAZARD. FROM THE
LIST OF TOXIC CHEMICALS, THIS PRODUCT CONTAINS: XYLENE, COBALT
COMPOUNDS, TOLUENE.